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E

Endothermic Reaction

A reaction that absorbs heat from the surroundings (ΔH > 0).

Enthalpy (H)

A thermodynamic state function defining the total heat content of a system at constant pressure.

Enthalpy Change (ΔH)

The heat flow (q) at constant pressure. A negative value indicates an exothermic reaction, while a positive value indicates an endothermic reaction.

Exothermic Reaction

A reaction that releases heat to the surroundings (ΔH < 0).

F

First Law of Thermodynamics

The total energy of a system and its surroundings remains constant.

H

Hess's Law

The enthalpy change for a reaction is the sum of the enthalpy changes for the individual steps of the reaction.

I

Internal Energy (U)

The sum of all possible kinds of energy present in a substance.

S

Standard Enthalpy of Combustion (ΔH°comb)

The enthalpy change when 1 mole of a substance burns completely in oxygen under standard conditions.

Standard Enthalpy of Formation (ΔH°f)

The enthalpy change when 1 mole of a substance is formed from its elements in their standard states.

Standard State

A commonly accepted set of conditions (1 bar pressure, 1 M concentration for solutions, and usually 298.15 K) used as a reference point for thermodynamic properties.


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